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Fuel Cycle & Waste Management
Devoted to all aspects of the nuclear fuel cycle including waste management, worldwide. Division specific areas of interest and involvement include uranium conversion and enrichment; fuel fabrication, management (in-core and ex-core) and recycle; transportation; safeguards; high-level, low-level and mixed waste management and disposal; public policy and program management; decontamination and decommissioning environmental restoration; and excess weapons materials disposition.
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Utility Working Conference and Vendor Technology Expo (UWC 2024)
August 4–7, 2024
Marco Island, FL|JW Marriott Marco Island
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Virginia utility considers SMRs
Dominion Energy Virginia has issued a request for proposals from leading nuclear companies to study the feasibility of putting a small modular reactor at its North Anna nuclear power plant.
While the utility says it is not a commitment to build an SMR at the site, the RFP is “an important first step in evaluating the technology and the North Anna site to support Dominion Energy customers’ future energy needs consistent with the company’s most recent Integrated Resource Plan.”
Joonhong Ahn, Shinichi Nakayama
Nuclear Technology | Volume 97 | Number 3 | March 1992 | Pages 323-335
Technical Paper | Radioactive Waste Management | doi.org/10.13182/NT92-A34640
Articles are hosted by Taylor and Francis Online.
Numerical results are presented for an analysis of diffusion of237Np, a redox-sensitive radionuclide, in engineered barriers consisting of overpack and bentonite-filled buffer regions, with oxidation-reduction kinetics of neptunium with iron and dissolved oxygen. Steady-state distributions of Fe(II) and dissolved oxygen are first obtained by considering the oxidation reaction of Fe(II) with oxygen. Based on these profiles, the neptunium diffusion models for pH 6.5 and 9.0 are established. Analytical or finite element solutions are obtained for the corresponding mathematical problems. At pH 9.0, even if dissolved oxygen intrudes on the buffer region from the rock/buffer interface, the penetration of oxygen into the overpack region and to the surface of the waste solid can be avoided. Thus, less soluble, strongly sorbing Np(IV) is released from the waste solid. At pH 6.5, dissolved oxygen can reach the waste surface. Weakly sorbing, soluble Np(V) is released from the waste solid. Although the released Np(V) is reduced to Np(IV) by Fe(II) in the overpack region, the Np(IV) is quickly oxidized by Fe(III) and dissolved oxygen at the overpack-buffer interface. Neglecting the existence of dissolved oxygen and assuming that the repository is kept under a reducing environment so that only Np(IV) migrates might lead to quite an optimistic estimate of the neptunium release rate from the engineered barriers.