Analytic models have been developed for evaluating hazards to nuclear plants from hazardous-materials accidents in the vicinity of the plant. In particular, these models permit the evaluation of hazards from such accidents occurring on surface traffic routes near the plant. The analysis uses statistical information on accident rates, traffic frequency, and cargo-size distribution along with parameters describing properties of the hazardous cargo, plant design, and atmospheric conditions, to arrive at a conservative estimate of the annual probability of a catastrophic event. Two of the major effects associated with hazardousmaterials accidents, explosion and release of toxic vapors, are treated by a common formalism which can be readily applied to any given case by means of a graphic procedure. As an example, for a typical case it is found that railroad shipments of chlorine in 55-ton tank cars constitute a greater hazard to a nearby nuclear plant than equally frequent rail shipments of explosives in amounts of 10 tons.