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W. Breitung, K. O. Reil
Nuclear Science and Engineering | Volume 101 | Number 1 | January 1989 | Pages 26-40
Technical Paper | doi.org/10.13182/NSE89-A23592
Articles are hosted by Taylor and Francis Online.
Newly developed in-pile techniques were used to measure the saturation vapor pressure of pure UO2.01, reactor grade UO2.08, and reactor grade (U0.77Pu0.23)O2.09 between 2000 and 3700 kJ/kg. The results for all three fuel types can be described by log Psat (z) = -9.7652 + 8.0934 × 10-3z - 2.0515 × 10-6z2 + 1.9013 × 10-10z3 with z = h-h298 in kilojoules per kilogram and psat in megapascals. The data were converted to the pressure-temperature format and compared to earlier out-of-pile vapor pressure measurements. All out-of-pile measurements that were performed close to a vapor-liquid equilibrium state agree very well with the in-pile results. The following relation is proposed for the p-T saturation line of liquid UO2: log psat (T) = 15.961 - 26974/T - 2.7600 log T, with psat in megapascals and T in degrees kelvin. Because no significant differences were found for all three fuel types investigated, the same saturation vapor pressure is recommended for liquid-metal fast breeder reactor (LMFBR) typical (U,Pu) mixed oxides under LMFBR core disassembly conditions.