Cross sections for the 63Cu(n,α)60Co reaction have been measured by activation for neutron energies from threshold to 10 MeV relative to well-known 238U fission cross sections. The data obtained are compared with values from the literature and the resulting spectrum-averaged cross sections based on the new results are given for the 235U thermal fission and 252Cf spontaneous fission neutron field. The new results indicate that the long-standing discrepancy between differential and integral data for the reaction 63Cu(n,α)60Co has been eliminated.